This role play would involve a rather unscrupulous man who is equally brilliant and able to pass himself off as a plastic surgeon. He was born into wealth and money is not what motivates him. He has spent many years perfecting his technique as he awaits the woman whom he will look upon as the canvas he shall work his masterpiece.
The surgery surpasses even his highest expectations. However unknown to his patient he also worked at altering her personality to suit his desires. Knowing the woman will be the picture of physical perfection he wants her to himself and therefore uses his experimental procedure to implant in her a desire for him. Also with this desire is a complete personality change he hopes to work into her making her submissive to him.
This does not work so well. What happens is she becomes the opposite. She tries to make him jealous by stalking other men and often torturing them once she beds them. He only finds out by piecing things together and reading about a stalker matching her description in the paper.
To him she feigns desire while perhaps hiding a desire to destroy him. However, she is stopped before she can go any further and the rest of the story would deal with how he must forget mind control and instead alter her personality by physical training.